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Ability of additives and certain synthetic lubricants to resist chemical decomposition (hydrolysis) in the presence of water.

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COMPOUND

(1) chemically speaking, a distinct substance formed by the combination of two or more elements in definite proportions by weight and possessing physical and chemical properties different from those of the combining elements. (2) in petroleum processing, generally connotes fatty oils and similar materials foreign to petroleum added to lubricants to impart special properties.

CORROSION INHIBITOR

Additive for protecting lubricated metal surfaces against chemical attack by water or other contaminants. There are several types of corrosion inhibitors. Polar compounds wet the metal surface preferentially, protecting it with a film of oil. Other compounds may absorb water by incorporating it in a water-in-oil emulsion so that only the oil touches the metal surface. Another type of corrosion inhibitor combines chemically with the metal to present a non- reactive surface.

False brinelling

False brinelling of needle roller bearings is actually a fretting corrosion of the surface since the rollers are the I.D. of the bearing. Although its appearance is similar to that of brinelling, false brinelling is characterized by attrition of the steel, and the load on the bearing is less than that required to produce the resulting impression. It is the result of a combination of mechanical and chemical action that is not completely understood, and occurs when a small relative motion or vibration is accompanied by some loading, in the presence of oxygen.

CATALYST

A substance which speeds a chemical action without undergoing a chemical change itself during the process. Now used in catalytic converters to control amount of unburned hydrocarbons and CO in automobile exhaust.

COMPOUNDED OIL

A petroleum oil to which has been added other chemical substances.

ATOM

The smallest complete particle of an element, which can be obtained, yet which retains all physical and chemical properties of the element.

INHIBITOR

A substance that slows or prevents such chemical reactions as corrosion or oxidation.

SODA ASH

A common water treatment chemical, sodium carbonate.

POLYMERIZATION

The chemical combination of similar-type molecules to form larger molecules.

POLAR COMPOUND

A chemical compound whose molecules exhibit electrically positive characteristics at one extremity and negative characteristics at the other. Polar compounds are used as additives in many petroleum products. Polarity gives certain molecules a strong affinity for solid surfaces; as lubricant additives (oiliness agents), such molecules plate out to form a tenacious, friction- reducing film. Some polar molecules are oil-soluble at one end and water-soluble at the other end; in lubricants, they act as emulsifiers, helping to form stable oil-water emulsions. Such lubricants are said to have good metal-wetting properties. Polar compounds with a strong attraction for solid contaminants act as detergents in engine oils by keeping contaminants finely dispersed.
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